Properties of Formic Acid (CH2O2)

Formic acid, also known as methanoic acid, is a simple organic compound with the chemical formula CH2O2. It is a colorless, pungent-smelling liquid that occurs naturally in some plants and animal venoms. Formic acid is the simplest carboxylic acid and is widely used in various industrial applications, including the production of textiles and leather.

The following table provides a comprehensive list of formic acid properties in both SI and US customary/Imperial units at normal temperature and pressure (NTP).

Click on the icon to switch between Metric and Imperial units.

Table of Formic Acid Properties
Physical Properties
Metric
Molar Mass46.03 g/mol
Density1220 kg/m3
Dynamic Viscosity1.773 mPa·s
Surface Tension37.58 mN/m
Thermal PropertiesMetric
Melting Point8.3 °C
Boiling Point101 °C
Thermal Conductivity0.274 W/m·K
Specific Heat Capacity (Cp)2152 J/kg·K
Vapor Pressure4.6 kPa
Critical ConstantsMetric
Critical Temperature (Tc)315 °C
Critical Molar Volume (Vc)116 cm3/mol
Electrical PropertiesMetric
Relative Permittivity (εr) (25°C)51.1
Optical PropertiesMetric
Refractive Index (589 nm)1.3714
Hazardous DataMetric
Flash Point69 °C
Autoignition Temperature601 °C
Lower Flammability Limit18%
Upper Flammability Limit57%
NFPA Rating (Health)3
NFPA Rating (Fire)2
NFPA Rating (Reactivity)0

Unless stated otherwise, all values are taken at room temperature (approximately 20°C or 68°F) and 1 atm pressure. (1 atm = 101,325 Pa)

References: 1) Cardarelli, François. Materials Handbook: A Concise Desktop Reference. Switzerland: Springer International Publishing, 2018. 2) CRC Handbook of Chemistry and Physics, 97th Edition. United Kingdom: CRC Press, 2016-2017. 3) Yaws, Carl L. The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals. Netherlands: Elsevier Science, 2015. 4) Fire Protection Guide to Hazardous Materials, 14th Edition. United States: National Fire Protection Association, 2010.