Properties of Octane (C8H18)

Octane is a hydrocarbon compound found in gasoline that is used as a measure of its performance in internal combustion engines. The octane rating of gasoline indicates its resistance to knocking or pinging, which are undesirable forms of combustion that can lead to engine damage. The higher the octane rating, the more resistant the fuel is to knocking.

The following table provides a comprehensive list of octane properties in both SI and US customary/Imperial units at normal temperature and pressure (NTP).

Click on the icon to switch between Metric and Imperial units.

Table of Octane Properties
Physical Properties
Metric
Molar Mass114.23 g/mol
Density703 kg/m3
Dynamic Viscosity0.542 mPa·s
Surface Tension21.62 mN/m
Thermal PropertiesMetric
Melting Point-56.7 °C
Boiling Point125.6 °C
Thermal Conductivity0.1281 W/m·K
Coefficient of Thermal Expansion (αV) (25°C)1.16×10-3 1/°C
Vapor Pressure1.4 kPa
Critical ConstantsMetric
Critical Temperature (Tc)296 °C
Critical Pressure (Pc)2.48 MPa
Critical Molar Volume (Vc)492 cm3/mol
Electrical PropertiesMetric
Relative Permittivity (εr)1.948
Optical PropertiesMetric
Refractive Index (589 nm)1.397
Hazardous DataMetric
Flash Point13 °C
Autoignition Temperature206 °C
Lower Flammability Limit1%
Upper Flammability Limit6.5%
NFPA Rating (Health)1
NFPA Rating (Fire)3
NFPA Rating (Reactivity)0

Unless stated otherwise, all values are taken at room temperature (approximately 20°C or 68°F) and 1 atm pressure. (1 atm = 101,325 Pa)

References: 1) Cardarelli, François. Materials Handbook: A Concise Desktop Reference. Switzerland: Springer International Publishing, 2018. 2) CRC Handbook of Chemistry and Physics, 97th Edition. United Kingdom: CRC Press, 2016-2017. 3) Yaws, Carl L. The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals. Netherlands: Elsevier Science, 2015. 4) Fire Protection Guide to Hazardous Materials, 14th Edition. United States: National Fire Protection Association, 2010.