Properties of Chloroform (CHCl3)

Chloroform is a volatile organic compound with the chemical formula CHCl3. It is a colorless, heavy, sweet-smelling liquid that was historically used as an anesthetic in the 19th and early 20th centuries. However, due to its toxic and potentially harmful effects on the liver and nervous system, its use in medicine has been largely discontinued.

The following table provides a comprehensive list of chloroform properties in both SI and US customary/Imperial units at normal temperature and pressure (NTP).

Click on the icon to switch between Metric and Imperial units.

Table of Chloroform Properties
Physical Properties
Metric
Molar Mass119.378 g/mol
Density1489 kg/m3
Dynamic Viscosity0.556 mPa·s
Surface Tension27.32 mN/m
Thermal PropertiesMetric
Melting Point-63.5 °C
Boiling Point61.2 °C
Thermal Conductivity0.1185 W/m·K
Coefficient of Thermal Expansion (αV)1.21×10-3 1/°C
Vapor Pressure21.3 kPa
Critical ConstantsMetric
Critical Temperature (Tc)263 °C
Critical Pressure (Pc)5.5 MPa
Critical Molar Volume (Vc)237 cm3/mol
Electrical PropertiesMetric
Relative Permittivity (εr)4.8069
Optical PropertiesMetric
Refractive Index (589 nm)1.4459
Hazardous DataMetric
NFPA Rating (Health)2
NFPA Rating (Fire)0
NFPA Rating (Reactivity)0

Unless stated otherwise, all values are taken at room temperature (approximately 20°C or 68°F) and 1 atm pressure. (1 atm = 101,325 Pa)

References: 1) Cardarelli, François. Materials Handbook: A Concise Desktop Reference. Switzerland: Springer International Publishing, 2018. 2) CRC Handbook of Chemistry and Physics, 97th Edition. United Kingdom: CRC Press, 2016-2017. 3) Yaws, Carl L. The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals. Netherlands: Elsevier Science, 2015. 4) Fire Protection Guide to Hazardous Materials, 14th Edition. United States: National Fire Protection Association, 2010.