Acetic Anhydride (C4H6O3)

Acetic anhydride, also known as ethanoic anhydride, is a chemical compound with the formula C4H6O3. It is a colorless, pungent-smelling liquid and is considered an important reagent in organic synthesis and the production of various chemicals and pharmaceuticals.

The following table provides a comprehensive list of acetic anhydride properties in both SI and US customary/Imperial units at normal temperature and pressure (NTP).

Click on the icon to switch between Metric and Imperial units.

Table of Acetic Anhydride Properties
Physical Properties
Metric
Molar Mass102.09 g/mol
Density1082 kg/m3
Dynamic Viscosity0.91 mPa·s
Surface Tension32.65 mN/m
Thermal PropertiesMetric
Melting Point-74 °C
Boiling Point139 °C
Thermal Conductivity0.164 W/m·K
Specific Heat Capacity (Cp)1830 J/kg·K
Coefficient of Thermal Expansion (αV)1.12×10-3 1/°C
Vapor Pressure0.53 kPa
Critical ConstantsMetric
Critical Temperature (Tc)333 °C
Critical Pressure (Pc)4 MPa
Critical Molar Volume (Vc)294 cm3/mol
Electrical PropertiesMetric
Relative Permittivity (εr)22.45
Optical PropertiesMetric
Refractive Index (589 nm)1.39
Hazardous DataMetric
Flash Point49 °C
Autoignition Temperature316 °C
Lower Flammability Limit2.7%
Upper Flammability Limit10.3%
NFPA Rating (Health)3
NFPA Rating (Fire)2
NFPA Rating (Reactivity)1

Unless stated otherwise, all values are taken at room temperature (approximately 20°C or 68°F) and 1 atm pressure. (1 atm = 101,325 Pa)

References: 1) Cardarelli, François. Materials Handbook: A Concise Desktop Reference. Switzerland: Springer International Publishing, 2018. 2) CRC Handbook of Chemistry and Physics, 97th Edition. United Kingdom: CRC Press, 2016-2017. 3) Yaws, Carl L. The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals. Netherlands: Elsevier Science, 2015. 4) Fire Protection Guide to Hazardous Materials, 14th Edition. United States: National Fire Protection Association, 2010.