Melting Point of Common Esters

The melting points of esters can vary widely depending on their specific chemical structure. The following table provides a comprehensive list of melting point values for common esters at 1 atmospheric (atm) pressure. (1 atm = 101,325 Pa)

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Melting Point of Esters
Methyl acetate (C3H6O2)-98
Ethyl acetate (C4H8O2)-83.6
Butyl acetate (C6H12O2)-77
Isopropyl acetate (C5H10O2)-73
Propyl acetate (C5H10O2)-93
Ethyl butyrate (C6H12O2)-97
Methyl propionate (C4H8O2)-88
Ethyl propionate (C5H10O2)-74
Isobutyl acetate (C6H12O2)-98.8
Butyl butyrate (C8H16O2)-91.5
Ethyl formate (C3H6O2)-80
Butyl formate (C5H10O2)-90
Methyl butyrate (C5H10O2)-95
Propyl butyrate (C7H14O2)-95
Methyl isobutyrate (C5H10O2)-85
Ethyl isobutyrate (C6H12O2)-88
Butyl isobutyrate (C8H16O2)-88
Isopropyl butyrate (C7H14O2)-95
Isobutyl butyrate (C8H16O2)-88
Methyl valerate (C6H12O2)-91
Ethyl valerate (C7H14O2)-91
Butyl valerate (C9H18O2)-93
Isopropyl valerate (C8H16O2)-63
Isobutyl valerate (C9H18O2)-93
Methyl hexanoate (C7H14O2)-71
Ethyl hexanoate (C8H16O2)-67
Butyl hexanoate (C10H20O2)-64
Isobutyl hexanoate (C10H20O2)-64
Methyl octanoate (C9H18O2)-40
Ethyl octanoate (C10H20O2)-43
Butyl octanoate (C12H24O2)-43
Isopropyl octanoate (C11H22O2)-46
Methyl decanoate (C11H22O2)-18
Ethyl decanoate (C12H24O2)-20
Methyl dodecanoate (C13H26O2)5
Ethyl dodecanoate (C14H28O2)-2
Butyl dodecanoate (C16H32O2)-7
Isopropyl dodecanoate (C15H30O2)4
Methyl benzoate (C8H8O2)-12
Ethyl benzoate (C9H10O2)-34
Butyl benzoate (C11H14O2)-22
Phenethyl acetate (C10H12O2)-31
References: 1) Cardarelli, François. Materials Handbook: A Concise Desktop Reference. Switzerland: Springer International Publishing, 2018. 2) CRC Handbook of Chemistry and Physics, 97th Edition. United Kingdom: CRC Press, 2016-2017. 3) Yaws, Carl L. The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals. Netherlands: Elsevier Science, 2015. 4) Occupational Safety and Health Administration (OSHA): The National Institute for Occupational Safety and Health (NIOSH). 5) Fire Protection Guide to Hazardous Materials, 14th Edition. United States: National Fire Protection Association, 2010.