Melting Point of Common Halides

The melting points of halides can vary widely depending on the specific halide and its composition. The following table provides a curated list of melting point values for common halides at 1 atmospheric (atm) pressure. (1 atm = 101,325 Pa)

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Melting Point of Halides
Hydrogen Fluoride (HF)-83.6
Hydrogen Chloride (HCl)-114.2
Hydrogen Bromide (HBr)-87
Hydrogen Iodide (HI)-50.8
Sodium Fluoride (NaF)993
Sodium Chloride (NaCl)800
Sodium Bromide (NaBr)755
Sodium Iodide (NaI)660
Potassium Fluoride (KF)858
Potassium Chloride (KCl)770
Potassium Bromide (KBr)730
Potassium Iodide (KI)681
Calcium Fluoride (CaF2)1418
Calcium Chloride (CaCl2)775
Calcium Bromide (CaBr2)730
Calcium Iodide (CaI2)780
Magnesium Fluoride (MgF2)1263
Magnesium Chloride (MgCl2)714
Magnesium Bromide (MgBr2)711
Magnesium Iodide (MgI2)634
Aluminum Fluoride (AlF3)1290 (sublimes)
Aluminum Chloride (AlCl3)180 (sublimes)
Aluminum Bromide (AlBr3)97.5
Aluminum Iodide (AlI3)188
Zinc Chloride (ZnCl2)290
Zinc Bromide (ZnBr2)394
Zinc Iodide (ZnI2)446
Silver Fluoride (AgF)435
Silver Chloride (AgCl)455
Silver Bromide (AgBr)430
Silver Iodide (AgI)558
Copper(I) Chloride (CuCl)430
Copper(I) Bromide (CuBr)497
Copper(I) Iodide (CuI)606
Copper(II) Fluoride (CuF2)836
Copper(II) Chloride (CuCl2)630
Copper(II) Bromide (CuBr2)498
Iron(II) Fluoride (FeF2)970
Iron(II) Chloride (FeCl2)677
Iron(II) Bromide (FeBr2)690
Iron(II) Iodide (FeI2)587
Iron(III) Chloride (FeCl3)304
Iron(III) Bromide (FeBr3)200 (decomposes)
References: 1) Cardarelli, François. Materials Handbook: A Concise Desktop Reference. Switzerland: Springer International Publishing, 2018. 2) CRC Handbook of Chemistry and Physics, 97th Edition. United Kingdom: CRC Press, 2016-2017. 3) Yaws, Carl L. The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals. Netherlands: Elsevier Science, 2015. 4) Occupational Safety and Health Administration (OSHA): The National Institute for Occupational Safety and Health (NIOSH).