Boiling Point of Common Acids

The boiling point of acids varies depending on their specific chemical composition. Acids are diverse compounds, and their boiling points are influenced by factors such as molecular size, intermolecular forces, and the presence of hydrogen bonding.

The following table provides a comprehensive list of boiling point values for common acids under 1 atmospheric (atm) pressure. (1 atm = 101,325 Pa)

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Boiling Point of Acids
Acetic Acid (CH3COOH)Organic117.9
Acetyl Chloride (CH3COCl)Organic51
Acetylsalicylic Acid (C9H8O4)OrganicDecomposes at 140
Aluminum Chloride (AlCl3)InorganicSublimes at 180
Antimony Pentafluoride (SbF5)Inorganic141
Benzoic Acid (C7H6O2)Organic249
Boric Acid (H3BO3)Inorganic300
Boron Trifluoride (BF3)Inorganic-100
Butyric Acid (C4H8O2)Organic163.5
Caproic Acid (C6H12O2)Organic205
Carbonic Acid (H2CO3)Inorganic333.6
Chromic Acid (H2CrO4)InorganicDecomposes at 250
Citric Acid (C6H8O7)OrganicDecomposes at 175
Formic Acid (HCOOH)Organic101
Glycolic Acid (C2H4O3)Organic100
Hydrobromic Acid (HBr)Inorganic-66.7
Hydrochloric Acid (HCl)Inorganic-85
Hydrofluoric Acid (HF)Inorganic19.5
Hydrogen Cyanide (HCN)Inorganic25.6
Hydrogen Peroxide (H2O2)Inorganic150.2
Hydrogen Selenide (H2Se)Inorganic-41.3
Hydrogen Sulfide (H2S)Inorganic-60
Hydrogen Telluride (H2Te)Inorganic-2
Hydroiodic Acid (HI)Inorganic-35.5
Hypofluorous Acid (HFO)InorganicDecomposes at 0
Iron(iii) Chloride (FeCl3)Inorganic316
Lactic Acid (C3H6O3)Organic122 at 15 mmHg
Linoleic Acid (C18H32O2)Organic229 at 16 mmHg
Malonic Acid (C3H4O4)OrganicDecomposes at 135
Nitric Acid (HNO3)Inorganic83
Oleic Acid (C18H34O2)Organic360
Oxalic Acid (C2H2O4)OrganicSublimes at 157
Palmitic Acid (C16H32O2)Organic351
Peracetic Acid (C2H4O3)Organic110
Perchloric Acid (HClO4)InorganicDecomposes at 90
Phosphoric Acid (H3PO4)Inorganic212
Propionic Acid (C3H6O2)Organic141
Stearic Acid (C18H36O2)Organic371
Succinic Acid (C4H6O4)Organic235
Sulfuric Acid (H2SO4)Inorganic337
Trichloroacetic Acid (C2HCl3O2)Organic198
Triflic Acid (CF3SO3H)Organic162
Valeric Acid (C5H10O2)Organic186
References: 1) CRC Handbook of Chemistry and Physics, 97th Edition. United Kingdom: CRC Press, 2016-2017. 2) Cardarelli, François. Materials Handbook: A Concise Desktop Reference. Switzerland: Springer International Publishing, 2018. 3) Occupational Safety and Health Administration (OSHA): The National Institute for Occupational Safety and Health (NIOSH). 4) Yaws, Carl L. The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals. Netherlands: Elsevier Science, 2015. 5) Fire Protection Guide to Hazardous Materials, 14th Edition. United States: National Fire Protection Association, 2010.